The Hydrogen Economy, Hydrogen Sources, and the Science Behind These

The hydrogen-filled Hindenburg in 1936 or 1937. Photo from DeGolyer Library at Southern Methodist University.

THE HYDROGEN ECONOMY

The hydrogen economy is a hypothetical future in which energy can be bought, sold, stored, and transported in a currency of hydrogen, much like today’s energy is often exchanged in electricity. Because hydrogen doesn’t need to be attached to the electricity grid, it can be used in forms of transportation like buses and cars.

The end-user of the hydrogen, for example an automobile driver, doesn’t experience significant pollution beyond the formation of water from burning the hydrogen.

For more details about the hydrogen economy see here.

Hydrogen, a gas, isn’t a fuel like gasoline or coal; hydrogen is a way to store and transport energy made from other fuels, like a battery or electricity. Unlike fossil fuels, pure hydrogen isn’t stable, so forming hydrogen in the first place requires energy and produces carbon dioxide, and storing hydrogen involves special considerations because this light gas is very flammable and also quickens rust and oxidation in pipelines and storage containers.

HOW HYDROGEN IS DIFFERENT FROM FOSSIL FUELS

Allowing hydrogen (a gas) to burn in the presence of oxygen releases that stored energy in the form of heat. Hydrogen can also be reacted in a fuel cell to produce electricity. In either case, electricity or heat can then be used to power cars or any number of other devices. Gasoline, biofuels, wood, and other carbon-based fuels all produce carbon dioxide when they are burned, and rising carbon dioxide levels are widely implicated in climate change. Burning hydrogen produces energy, water and a few trace compounds, but it doesn’t produce carbon dioxide.

2 H2 (hydrogen gas) + O2 (oxygen gas) = 2 H2O (water vapor) + energy

It’s unclear what widespread emission of water vapor could do. According to recent published estimates, atmospheric water vapor is responsible for 75 percent of the greenhouse effect. However, water vapor can condense, and it’s naturally-occurring in the atmosphere. It is much easier to trap and transform to liquid than the carbon dioxide normally emitted by burning gasoline. Carbon dioxide won’t form a liquid at atmospheric temperatures and will solidify into dry ice only below -108.4 Fahrenheit, so proponents say it can be easier to trap the vapor in hydrogen-powered machines.

If the energy used to generate and purify and store and ship hydrogen doesn’t require emitting greenhouse gases or toxics, proponents argue that hydrogen is a clean alternative.

SOURCES OF HYDROGEN: THE UNFORTUNATE REALITY TODAY

Hydrogen, not carbon, is the most prevalent atom in the human body. There are two hydrogen atoms in every water molecule, and as many as hundreds of hydrogen atoms on the basic building blocks of life, from DNA to plant fibers. Nonetheless, harvesting the hydrogen atoms out of any of these structures to make hydrogen fuel isn’t easy because hydrogen likes to be bonded to carbon or oxygen; it doesn’t like to be elemental gas.

To produce pure hydrogen today, industries use primary fuel source like petroleum, natural gas, coal, or biomass. Through chemical processing, the hydrogen atoms are stripped from the fuel by way of an input of energy from electricity (more than 80 percent of which comes from fossil fuels in the United States). Furthermore, the leftover material from the stripping is carbon dioxide, the same carbon dioxide that would have been produced if the fuel was burned in an engine.

The reactions for various fuel to hydrogen conversions can be found on the U.S. Department of Energy website here.

Hydrogen can also be produced, at great energy loss, through the electrolysis of water: using electricity, water is divided into its constituents, hydrogen and oxygen. However, water electrolysis is the least carbon-neutral hydrogen production method, and it is very expensive ($3 to $6 per kilogram instead of a little more than $1 in the case of using coal for hydrogen), according to the U.S. Energy Information Administration. All hydrogen production methods result in a net energy loss.

 

 

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What Is A Nuclear Reaction?

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Photovoltaic Cells, Solar Power, and LEDs

Most of the world’s energy can go back to our sun. Every day we are heated by its electromagnetic rays, and plants use the sun’s energy to make sugars and ultimately proteins and other good things to eat. Fossil fuels were also once made from these plant and other organisms that relied on the sun’s energy millions of years ago. Today, humans can convert the sun’s energy directly into electricity, through solar thermal and solar photovoltaic systems.

SOLAR THERMAL OR PHOTOVOLTAIC?

Solar panels, also called solar thermal, convert sunlight to heat and then heat to electricity. Photovoltaic cells, or solar cells, convert sunlight directly into electric current by way of carefully-engineered semiconductor materials.

Though solar photovoltaics are more efficient converters of sunlight, they are also more expensive.

As of May 2011, the world’s largest solar power plant is a concentrating solar thermal power plant in the Mohave desert in California. Solar Energy Generating Systems has a capacity of 310 megawatts and uses parabola-shaped reflective troughs to concentrate electromagnetic radiation.

The world’s largest solar photovoltaic plant is probably the Sarnia Solar Project in Ontario, Canada. It has a capacity of roughly 80 megawatts.

HOW SOLAR THERMAL WORKS

Sunlight heats a design element (water, air, chemical fluids), and that thermal energy is transmitted for other applications, such as heating water, heating space, or generating electricity. In solar thermal power plants, sunlight heats a specialized fluid, which in turn heats water into steam, which can run turbines and produce electricity.

Solar thermal power plants use concentrators that bounce the sunlight off elliptical mirrors to a central tube, in which the specialized fluid lies.

HOW PHOTOVOLTAICS WORK

Photovoltaic cells are made of specialized diodes. Electrons (natural components of atoms) in the photovoltaic cells absorb light, which excites them to a state where they can be conducted as electrical current. This difference in energy, between the valence band (the state of a normal electron staying around its home atom) to the conduction band (electron free to move between atoms) is called the band gap.

Solar photovoltaic farm in Indonesia. Photo by Chandra Marsono.

Well-engineered photovoltaics have a band gap that coincides with the energies of as broad a spectrum of light as possible, to convert the maximum amount of the sunlight into electricity.

As sunlight energy pops electrons into the conduction band and away from their home atoms, an electric field is produced. The negatively-charged electrons separate from the positively-charged “holes” they leave behind, so that when electrons are freed into the conduction band, they move as electric current in the electric field, electricity.

PHOTOVOLTAICS ARE MADE OF SPECIALIZED MATERIALS

An ever-expanding variety of semiconductor materials can be used to make solar cells; universities and companies worldwide are researching these options, from special bio-plastics to semiconductor nanocrystals. Nonetheless, the photovoltaic cells available today require precise manufacturing conditions and are therefore far more expensive to produce than solar panels.

Silicon has to be processed under clean room conditions — carefully regulated atmospheres — to remove impurities and prevent introducing contaminants, both of which can change the band gap. Thin film-based photovoltaics require special production methods, like chemical vapor deposition. Semiconductor processing also uses strong acids and often dangerous chemicals for etching.

Today, commercially-sold cells are made from purified silicon or other crystalline semiconductors like cadmium telluride or copper indium gallium selenide.

WHERE DO WE GET THE STARTING MATERIALS?

Silicon is plentiful in the Earth’s crust. Cadmium is a readily available but highly toxic heavy metal, as is arsenic, another chemical used in some cells. As tellurium demand is only recently rising in response to solar demand, it’s unknown what the global supply is for this unusual element but it may be quite abundant. Photovoltaics are a lively area of research, and the future production and environmental costs of starter materials, production, and pollution are difficult to predict.

California, Massachusetts, Ohio, and Michigan produced the most photovoltaics in 2009. However, that year, 58 percent of photovoltaics were imports, primarily from Asian countries like China, Japan, and the Philippines.

LED TECHNOLOGY: MORE THAN HEADLAMPS

Photovoltaic cells work in the opposite direction of light-emitting diodes, or LEDs. LEDs are used interchangeably with other lighting, like light bulbs. However, LED’s work in a completely different manner, far closer to the way photovoltaics work.

Click here see a bar chart comparing how much energy is used by various light sources.

LEDs absorb energy in the form of electricity, exciting electrons into the conduction band. When the electrons in the semiconductor material drop back into the valence band from the conduction band, they emit energy in the form of photons, or electromagnetic radiation.

It’s a highly efficient process because energy isn’t wasted on producing heat, which happens with standard tungsten filament bulbs. LEDs also last a much longer time as they do not have filaments to burn out, and because they are very small and several units are used to replace one large traditional lamp, they do not all burn out at once. That makes LEDs a good choice for stoplights or other safety critical applications.

 

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Forms of Energy: Motion, Heat, Light, Sound

What forms of energy is Raul using to move his LEGO car?

When he was a teenager in Romania, Raul Oaida became obsessed with building things: a jet-engine bike, a tiny spaceship, a LEGO car that runs on air. Why? Well, why not?

You can see more cool stories about energy at The Adaptors website.

Like video and audio? Check out The Adaptors Podcast.

 

Energy comes in two basic forms: potential and kinetic

Potential Energy is any type of stored energy. It can be chemical, nuclear, gravitational, or mechanical.

Kinetic Energy is found in movement. An airplane flying or a meteor plummeting each have kinetic energy. Even the tiniest things have kinetic energy, like atoms vibrating when they are hot or when they transmit sound waves. Electricity is the kinetic energy of flowing electrons between atoms.

energy_forms_pie-chartEnergy can shift between forms, but it is never destroyed or created.

A car transforms the potential energy trapped in gasoline into various types of energy that help the wheels turn and get the car to move. Most of the energy is converted to thermal energy, which is an unorganized form of energy that is difficult to convert into a useful form.

Power plants transform one form of energy into a very useful form, electricity. Coal and natural gas plants use the chemical potential energy trapped in fossil fuels. Nuclear power plants change the nuclear potential energy of uranium or plutonium into electricity too. Wind turbines change the kinetic energy of air molecules in wind into electricity. Hydroelectric power plants take advantage of the gravitational potential energy of water as it falls from the top of a dam to the bottom.

These transformations are hardly perfect. An efficient fossil fuel power plant loses more than half of the energy it creates to forms other than electricity, such as heat, light, and sound.

Forms of Potential Energy

GRAVITATIONAL

Systems can increase gravitational energy as mass moves away from the center of Earth or other objects that are large enough to generate significant gravity (our sun, the planets and stars).

For example, the farther you lift an anvil away from the ground, the more potential energy it has. Lifting the anvil is called work, which is an interaction in which energy is transferred from one system (the person) to another (the anvil). The person has to do more work in order to carry the anvil higher, and the higher the anvil is carried, the more gravitational potential energy is stored in the anvil. If the anvil is dropped, that potential energy transforms to kinetic energy as the anvil moves faster and faster toward Earth.

CHEMICAL

Chemical energy is stored in the bonds between the atoms in compounds. This stored energy is transformed when bonds are broken or formed through chemical reactions. Like letters of the alphabet that can be rearranged to form new words with very different meanings, atoms move around during chemical reactions, and they form new compounds with vastly different personalities.

When we burn sugar (a compound made of the elements hydrogen, oxygen, and carbon) in our bodies, the elements are reorganized into water and carbon dioxide. These reactions both absorb and release energy, but the overall result is that we get energy from the sugar, and our bodies use that energy to do work.

Chemical reactions that produce net energy are exothermic. When wood is burned, the chemical reactions taking place are exothermic. Electromagnetic and thermal energy are released. Only some chemical reactions release energy. Endothermic reactions need energy to start and to continue, such as by adding heat or light.

NUCLEAR

Today’s nuclear power plants are fueled by fission. Uranium or plutonium atoms are broken apart, freeing lots of energy. Hydrogen atoms in the sun experience nuclear fusion, combining to form helium and subsequently releasing large amounts of energy in the form of electromagnetic radiation and thermal energy.

Nuclear energy is the stored potential of the nucleus of an atom. Most atoms are stable on Earth; they keep their identities as particular elements, like hydrogen, helium, iron, and carbon, as identified in the Periodic Table of Elements. The number of protons in the nucleus tells you which element it is. Nuclear reactions change the fundamental identity of elements by splitting up an atom’s nucleus or fusing together more than one nucleus. These changes are called fission and fusion, respectively.

ELASTIC

Elastic energy can be stored mechanically in a compressed gas or liquid, a coiled spring, or a stretched elastic band. On an atomic scale, the stored energy is a temporary strain placed on the bonds between atoms, meaning there’s no permanent change to the material. These bonds absorb energy as they are stressed, and release that energy as they relax.

Forms of Kinetic Energy

MOTION

A moving object has kinetic energy. A basketball passed between players shows translational energy. That kinetic energy is proportional to the ball’s mass and the square of its velocity. To throw the same ball twice as fast, a player does more work and transfers four times the energy.

rotationalIf a player shoots a basketball with backspin or topspin, the basketball will also have rotational energy as it spins. Rotational energy is proportional to how many times it spins per second, as well as the ball’s mass, and the size and shape of the ball.

In shooting a basketball, players often try to add rotational energy as backspin, because it results in the greatest slowdown in speed when the basketball hits the rim or the backboard, increasing the chance that the ball stays near the basket. The opposite direction of spin, a topspin, can be used in games like tennis, because it will help speed up a ball after impact and lowers the angle it travels after the bounce.

THERMAL ENERGY AND TEMPERATURE

Thermal energy is directly related to temperature. We can’t see individual atoms vibrating, but we can feel their kinetic energies as temperature. When there’s a difference between the temperature of the environment and a system within it, thermal energy is transferred between them as heat.

tea kettleA hot cup of tea loses some of its thermal energy as heat flows from the tea to the air in the room. Over time, the tea cools to the same temperature as the room air. At the same time, the thermal energy in the room air increases due to heat transfer from the tea. However, the thermal capacitance of the room air is much larger than the tea, so the temperature of the air in the room increases by very little – so little that a person in the room wouldn’t notice it.

Heat  flows spontaneously from high temperature objects to nearby low temperature objects, until all objects reach the same temperature, called thermal equilibrium. Some materials are easier to heat up or cool down than others. The thermal capacitance, or heat capacity, of a material tells us how much energy it takes to raise that material one degree in temperature. A pound of water has greater thermal capacitance than the same amount of stainless steel, for example. In moments, an empty one pound pot on the stove heats to 212 degrees Fahrenheit (the boiling temperature of water). If you pour a pound of water into the pot, it will take much longer than the empty pot to reach the same temperature, because water needs more energy to get as hot as steel.

SOUND

Sound waves are made when stuff vibrates – like strings on an instrument or gas molecules in the air. Sound waves travel when the vibrating stuff causes stuff surrounding it to also vibrate. This happens in liquid, solid, or gaseous states. Sound cannot travel in a vacuum because a vacuum has no atoms to transmit the vibration.

Solids, liquids, and gases transmit sounds as waves, but the atoms that pass along the sound don’t travel the way photons do. The sound wave travels between atoms, like people passing along a “wave” in a sports stadium. Sounds have different frequencies and wavelengths (related to pitch) and different magnitudes (related to how loud).

Even though radio waves can transmit information about sound, they are a completely different kind of energy, called electromagnetic energy.

ELECTROMAGNETIC RADIATION

PlantElectromagnetic energy is the same as radiation or light. This type of energy can take the form of visible light, like the light from a candle or a light bulb, or invisible waves, like radio waves, microwaves, x-rays and gamma rays. Radiation — whether it’s coming from a candle or an x-ray tube — can travel in a vacuum. Sometimes physicists describe electromagnetic radiation as being composed of particles – tiny packets of energy called photons. Each photon has a characteristic frequency, wavelength, and energy, but all photons travel at the same speed, the speed of light, or nearly 1 billion feet per second.

Electromagnetic energy can be converted to the chemical energy stored in plants through photosynthesis, the process by which plants and algae use the sun’s radiation to turn carbon dioxide gas into sugar and carbohydrates.

ELECTRIC

Electric energy is to the kinetic energy of moving electrons, the negatively-charged particles in atoms. For more information about electricity, see Basics of Electricity.

 

-Anrica Deb

 

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Physics and How Machines Work

Machines are so complicated these days it’s difficult to quickly explain how they work. Nonetheless, today’s machines were built using the basic principles of physics that we began harnessing hundreds of years ago.

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Basics of Electricity and Circuits: How Energy Moves Through the Home

A BRIEF HISTORY OF ELECTRICITY

The first major use of electricity began in 1879, when Thomas Edison began installing incandescent lighting in notable locations like Wall Street in New York City. Edison wasn’t alone in his pursuit of electricity development, but he was the first to install integrated systems in conspicuous places.

At that time, Americans used various other light sources, like oil lamps, candles, and fires. A candle gives off only around a single watt’s worth of light. Calcium (or lime) lights could provide a lot of light, but it was a harsh light and reserved for conditions like the theater, hence the term in the limelight.

Most lighting was very poor – and often dangerous – in comparison to fluorescent bulbs, and electricity became popular quite quickly. By the turn of the century, other electric devices began to become available, and by the 1920s, Americans could purchase electric refrigerators, dishwashers, and washing machines.

The first electrical systems depended on extremely local power plants, within a few blocks, or even within the building. As time passed, electricity development became a regional responsibility, and today, the United States is split into many different systems of electricity distribution, including both regulated municipalities and for-profit utilities.

 

WHAT IS ELECTRICITY?

Electricity isn’t merely the existence of electrons but the flow, and it is their flow that provides power. It’s a little bit like gravity and the flow of water downhill. Water will move spontaneously downhill because of gravity. Electrons (like other charged particles) move spontaneously when they are in electric fields. An electric field is generated when there’s a difference in electric potential – called a voltage – just like a hill exists when there’s a difference in altitude.

Electricity is the flow of electrons, which themselves are small charged particles associated with atoms. Under neutral conditions, electrons stay with the atom or group of atoms that make up a compound. However, one electron is indistinguishable from another and can move from one atom to an adjacent one if the atoms make up a conducting material, like various metals.

Voltage can be thought of as the height of the hill. The bigger the voltage, the more electrons want to move, and the more power can be delivered.

Cataract Falls, Mount Tamalpais, California

Electrons moving can be diverted to do work, sort of in the same way that water traveling downhill can be diverted to run a mill or turbine.

The water’s kinetic energy is lost as it is used up in the turbine. Likewise, the electrons’ kinetic energy is lost when they are put to work in a device. The electrons don’t get destroyed in the process of losing energy, just as the water wouldn’t be destroyed.

 

ALTERNATING CURRENT

When you plug in something like a light, electrons flow from the plug, through the light, and back out through the plug. However, it’s not that simple, since we use what’s called alternating current, or AC, which means that the electrons flow one direction and then reverse direction. Alternating current makes it easy to change from a high voltage to a lower voltage. This change is made through a transformer.

 

ELECTRICITY IN THE HOME

Today, inside the home, electricity powers computers, televisions, telephones, lights, refrigerators, heaters, air conditioning, healthcare-related devices, video games, rechargeable toys, stereos, alarm systems, garage doors, ovens, stovetops, dishwashers, clothes washers, routers, can openers, DVD players, DVRs, and countless rechargeable devices like phones and electronic tablets.

Computers, televisions, and handheld electronic devices have become increasingly popular, while refrigeration, heating, and cooling have become more efficient. These recent trends in home electricity use have shifted the greater part of home energy needs from climate control to electronics.

 

A FUTURE FOR TELEVISION?

Today, most households have more than two televisions, with 88 percent of homes have two or more televisions in 2009. The average household had 2.5 televisions. In the same year, 79 percent had DVD players, 43 percent had DVRs, and 86 percent of households had one or more computers. Nielson reported in May, 2011 that for the first time in 20 years, television ownership is slightly down, perhaps in part because computers may be replacing the use of televisions, DVDs, VCRs, and video games.

 

More about home energy in the energy efficiency section.

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Historical Events in Nuclear Fission

As is the case with so many scientific fields, the history of nuclear physics and energy development has always been wrapped up with the history of modern warfare.

An unprecedented level of research went into the American bomb program, applying a rapidly evolving understanding of nuclear physics immediately to building a weapon. That investment spurred the rest of the world to pursue nuclear fission, often using the energy as an excuse for the weapons development. Rather than isolate nuclear energy from its less peaceable counterpart, the timeline incorporates all types of nuclear history.

Recent nuclear media coverage:

Germany begins shutting down old reactors and considers swearing off nuclear power entirely. Germany Dims Nuclear Plants, but Hopes to Keep Lights On.

New evidence that Japan’s troubled reactors were destined to malfunction, tsunami or not, in The Explosive Truth Behind Fukushima’s Meltdown.

Add more here. TK

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